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91.
[reaction: see text] A ruthenium porphyrin-catalyzed stereoselective intramolecular carbenoid C[bond]H insertion is described. Using [Ru(II)(TTP)(CO)] as catalyst, aryl tosylhydrazones are converted to 2,3-dihydrobenzofurans, 2,3-dihydroindoles, and beta-lactams in good yields and remarkable cis selectivity (up to 99%). Enantioselective synthesis of 2,3-dihydrobenzofurans is also achieved with [Ru(II)(D(4)-Por*)(CO)] as catalyst, and up to 96% ee is attained. 相似文献
92.
In this paper we study three-color Ramsey numbers. Let K
i,j
denote a complete i by j bipartite graph. We shall show that (i) for any connected graphs G
1, G
2 and G
3, if r(G
1, G
2)≥s(G
3), then r(G
1, G
2, G
3)≥(r(G
1, G
2)−1)(χ(G
3)−1)+s(G
3), where s(G
3) is the chromatic surplus of G
3; (ii) (k+m−2)(n−1)+1≤r(K
1,k
, K
1,m
, K
n
)≤ (k+m−1)(n−1)+1, and if k or m is odd, the second inequality becomes an equality; (iii) for any fixed m≥k≥2, there is a constant c such that r(K
k,m
, K
k,m
, K
n
)≤c(n/logn), and r(C
2m
, C
2m
, K
n
)≤c(n/logn)
m/(m−1)
for sufficiently large n.
Received: July 25, 2000 Final version received: July 30, 2002
RID="*"
ID="*" Partially supported by RGC, Hong Kong; FRG, Hong Kong Baptist University; and by NSFC, the scientific foundations of
education ministry of China, and the foundations of Jiangsu Province
Acknowledgments. The authors are grateful to the referee for his valuable comments.
AMS 2000 MSC: 05C55 相似文献
93.
Stanislaw Dzwigaj Lorenzo Stievano Michel Che 《Journal of Physics and Chemistry of Solids》2007,68(10):1885-1891
Fe-containing SiBEA zeolites were prepared by a two-step postsynthesis method: creation of vacant T-sites by dealumination of tetraethylammonium BEA zeolite with nitric acid and then impregnation of the resulting SiBEA zeolite with an aqueous solution of Fe(NO3)3. X-ray diffraction shows that iron is incorporated in SiBEA at lattice sites. The presence of Fe in its oxidation state +3 and at isolated tetrahedral sites for low metal content, was demonstrated by diffuse reflectance UV-vis, EPR and Mössbauer spectroscopy. For high iron content, diffuse reflectance UV-vis and Mössbauer spectra revealed the additional presence of extra-lattice FeOx oligomers and superparamagnetic Fe-oxyhydroxide. Mössbauer spectroscopy identified superparamagnetic Fe-oxyhydroxide as the main phase when basic conditions are used for the preparation. 相似文献
94.
95.
T. L. Che Q. C. Gao W. P. Zhang Z. X. Nan H. X. Li Y. G. Cai J. S. Zhao 《Russian Journal of Coordination Chemistry》2009,35(10):723-730
Coordination polymers, [Sm2(Pzdc)3(H2O)]
x
· 2xH2O (I) and [Nd2(Pzdc)3(H2O)]
x
· 2xH2O (II), were obtained by hydrothermal reactions with 2,3-pyrazinedicarboxylic acid (H2Pzdc) and the salts nitrates, and characterized by single crystal X-ray structure, thermogravimetric analysis, element analysis
and infrared spectroscopy. The X-ray crystal diffraction data indicates that two complexes crystal in a monoclinic system
with the space group P21/c, of the three dimensional framework. The Pzdc ligand in the complexes I and II adopts tetradentate, hexadentate, and heptadentate
bridging modes. The influences of coordination modes of the Pzdc ligand on the superstructural diversity is discussed. The
photoluminescent data suggest that the ligands act as efficient “antennas” sensitizing the luminescence of the Sm3+ ion. Complex I exhibits strong fluorescent emission bands in the solid state at room temperature. 相似文献
96.
Maolin Pan 《Insurance: Mathematics and Economics》2008,42(1):119-126
In this paper, we investigate the problems of convergence of experience-based ratemakings regarding the Esscher principle. In addition to the Bayes and the classical credibility premiums, we suggest a new credibility formula for the Esscher premium. Then we show the convergence of the Bayes and the newly defined credibility premiums towards the individual premium and point out that the classical credibility premium does not generally converge to the individual premium by presenting a sufficient and necessary condition under which the classical credibility Esscher premium converges to the individual premium. A simulation study is carried out to illustrate the theoretical conclusions. 相似文献
97.
98.
99.